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Dimethyl ether hydrogen bonding with water. он ethyl methyl ketone нн нн ethylamine h нн methyl propanoate. Which of the following would be expected to form hydrogen bonds with water. Dimethyl ether h f ch3 2 chloro 2 methylpropane ch3cch3 ci cyclohexane нн none of the above in which of the followi ing pure substances would hydrogen bonding be expected. An isotope effect is observed in water and methanol but not for dimethyl ether which cannot donate a hydrogen bond at its oxygen site.
Ether blocks hydrogen bonding completely and leads to drastic decreases of the clustering energies. The isotope effect and therefore the strength of the hydrogen bond network is more pronounced in water than in methanol. Consequently an ether has about the same solubility in water as the alcohol that is isomeric with it. This work will be described in a separate publication 13.
Ethers containing up to 3. For example dimethyl ether and ethanol both having the molecular formula c 2 h 6 o are completely soluble in water whereas diethyl ether. Ether molecules do have an oxygen atom however and engage in hydrogen bonding with water molecules.
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